The Messenger of Allah ﷺ permitted the use of ruqyah for the bite of a snake or scorpion.
رخص رسول الله ﷺ في الرقية من الحية والعقرب.
Ibn Majah (3517) narrated it, and Ibn Hibban (6101) graded it sahih, both from the hadith of Abu Ahwas, from Mughira, from Ibrahim, from Aswad, from Ayesha, and he mentioned it.Muslim (2193:53) narrated it through another route from Mughira, "The Messenger of Allah ﷺ gave permission to a household among the Ansar to perform ruqya for scorpion stings."