The Prophet ﷺ killed a scorpion while he was praying.
حدثنا محمد بن يحيى حدثنا الهيثم بن جميل حدثنا مندل
أن النبي ﷺ قتل عقربا وهو في الصلاة
No references are available.
[Its chain of transmission is daif]. Busiri said, "This chain includes Mindal bin Ali Anbari Kufi, who is daif, and his teacher Muhammad bin Abdullah Ibn Abu Rafi is also daif" (Taqrib). See also, no. 1297.